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=== Phonons with Negligible Polarities
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我们用 gamma 点的声子来近似弱极性的声子。
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用 gamma 点的声子来近似。
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Gamma 点的声子被用于
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Gamma 点的声子被用于近似参与拉曼散射的弱极性声子,无论入射配置。
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这个近似是因为这些声子的色散曲线在 Gamma 点附近连续且非常接近 Gamma 点,并且已经被广泛使用。
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// We investigate phonons at Gamma instead of the exact location near Gamma.
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Phonons at the #sym.Gamma point were used
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to approximate negligible-polar phonons that participating in Raman processes
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Phonons at the #sym.Gamma point were used to approximate negligible-polar phonons,
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regardless of the wavevector of the incident and scattered light.
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This approximation is widely adopted (cite) and justified by the fact that,
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although the phonons participating in Raman processes are not these strictly located at the #sym.Gamma point,
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they are very close to the #sym.Gamma point in reciprocal space
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(about 0.01 nm#super[-1] in back-scattering configurations with 532 nm laser light,
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which corresponds to only 1% of the smallest reciprocal lattice vector of 4H-SiC,
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see orange dotted line in @figure-discont),
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and their dispersion at #sym.Gamma point is continuous with vanishing derivatives.
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Therefore, negligible-polar phonons involved in Raman processes
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have nearly indistinguishable properties from those at the #sym.Gamma point.
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This approximation is based on the fact that
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the dispersion of these phonons is continuous and very close to the #sym.Gamma point,
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and has been widely adopted in the literature @_n-sic_2008.
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gamma 点处 18 个声子的表示。它们的拉曼张量的形状可以确定,但大小无法确定。
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18 个声子属于 12 个表示。拉曼张量的形状可以确定,大小不能。
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这些声子的拉曼张量的形状可以通过对称性分析来确定。
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Gamma 点声子满足 C#sub[6v] 点群对称性,18 个模式包含了 2A#sub[1] + 4B#sub[1] + 2E#sub[1] + 4E#sub[2] 共 12 个表示;
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其中简并表示(E1 和 E2)的拉曼张量的形状可以通过进一步考虑在 C#sub[2v] 点群中的表示来确定,如表所示。
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其中,B#sub[1] 模式具有零拉曼张量,不参与拉曼散射;
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其它表示的模式具有非零拉曼张量分量,可能可以在适当的偏振配置下在拉曼实验中观察到。
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然而,模式是否足够强以在实验中可见取决于其拉曼张量分量的大小,而仅通过对称性分析无法确定这些大小。
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// Representation of these 18 phonons, and the shape of their Raman tensors could be determined in advance.)
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Phonons at the #sym.Gamma point satisfy the C#sub[6v] point group symmetry,
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