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@@ -39,9 +39,9 @@ However, whether a mode is sufficiently strong to be experimentally visible
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We propose a method to estimate the magnitudes of the Raman tensors of these phonons based on symmetry analysis.
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This approach is founded on the assumption that the change in polarizability induced by atomic displacements in 4H-SiC
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is mainly determined by two factors: first- and second-nearest neighbors of the atom, and the symbol of charge corresponding to the atom,
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all other factors (mass, bond length, etc.) contribute only a small value.
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Consequently,
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is primarily determined by the first- and second-nearest neighbors of the atom and the sign of the atomic charge,
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while other factors (mass, bond length, etc.) only have small contributions.
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As a result,
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the phonon modes with the strongest Raman intensities can be predicted
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prior to first-principles calculations and experiments,
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and the Raman tensors of the calculated phonon modes can be estimated without additional first-principles computations.
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