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总共有 21 个声子模式。我们把它分成 18 个极性很小的和 3 个极性很强的两类。
// There are 21 phonons in total.
// We classified them into two categories: 18 negligible-polar phonons and 3 strong-polar phonons.
The phonons involved in Raman scattering are located in reciprocal space around the #sym.Gamma point,
and the exact positions are determined by the wavevectors of the incident and scattered light.
At each such position, there are 21 phonon modes (degenerate modes are counted as their multiplicity).
We classify these 21 phonons into two categories based on their polarities.
The 18 of 21 phonons are classified into negligible-polar phonons (i.e., phonons with zero or very weak polarity),
对应于不同拉曼入射配置(正入射、掠入射、边入射)的声子位于倒空间中的不同位置。
它们都位于 Gamma 点附近,与 Gamma 点的距离由入射光波长决定,而与 Gamma 点的相对位置则由入射方向决定。
对于每一个 Gamma 附近的点,都有 21 个声子模式(简并模式按简并数计)。
我们将这 21 个声子模式分为两类18 个极性可以忽略的声子模式(即极性为零或非常弱的声子),在拉曼散射过程中它们的电极性造成的效应可以忽略;
3 个强极性声子模式,在拉曼光谱中电极性效应是可观测的。
Phonons involved in different Raman incidence configurations (normal, grazing, and edge incidence)
are located at different positions in reciprocal space,
all of which are near the #sym.Gamma point,
with the distance from the #sym.Gamma point determined by the wavelength of the incident light,
and the relative position to the #sym.Gamma point determined by the direction of incidence.
For each such position around the #sym.Gamma point,
there are 21 phonon modes (degenerate modes are counted according to their multiplicity).
We classify these 21 phonon modes into two categories:
18 negligible-polar phonons (i.e., phonons with zero or very weak electrical polarity),
for which the effect of polarity can be ignored in the Raman scattering process;
and the other three phonons are strong-polar phonons,
and the other three strong-polar phonons,
where the polarity gives rise to observable effects in the Raman spectra.
这个分类是有意义的。从微观上讲,它也和原子的振动方向有关。