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@@ -10,7 +10,7 @@ This approximation is widely adopted (cite) and justified by the fact that,
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see orange dotted line in @figure-discont),
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and their dispersion at #sym.Gamma point is continuous with vanishing derivatives.
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Therefore, negligible-polar phonons involved in Raman processes
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have nearly indistinguishable frequencies and vibration amplitudes from those at the #sym.Gamma point.
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have nearly indistinguishable properties from those at the #sym.Gamma point.
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#include "figure-discont.typ"
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@@ -85,3 +85,5 @@ Besides, there are small peeks at xxx,
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#include "table-nopol.typ"
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#include "figure-raman.typ"
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// TODO: 解释为什么 E1 可以看到
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@@ -8,28 +8,36 @@
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// 若考虑到到入射光不是严格沿着 z 方向,而是有一个小的角度(例如 10 度),则此时有一个声子模式沿着 x 方向,另外两个声子模式则为 y-z 两个方向的混合。
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// (没有在图上表示)
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Strong-polar phonons heavily depend on the direction of their wavevectors
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due to long-range Coulomb interactions between atoms in semiconductors.
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This causes the strong-polar phonon modes corresponding to different incident light directions
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having different frequencies (i.e., discontinuity of colored lines near #sym.Gamma point in @figure-discont),
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and their vibration directions also vary accordingly.
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For incident laser propagating along the z direction,
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the relevant phonon modes are those along the A-#sym.Gamma line and symmetry of C#sub[6v] point group applies,
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leading to two modes (two peeks in Raman spectra),
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Strong-polar phonon modes caused by different incident light directions are different,
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due to long-range Coulomb interactions between atoms in semiconductors,
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showing discontinuity in the scattering spectra near the #sym.Gamma point (see @figure-discont).
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For incident light propagating along the z direction (phonon modes on the A-#sym.Gamma line),
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symmetry of C#sub[6v] point group applies and leading to two modes (two peeks in Raman spectra),
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including an E#sub[1] mode (pink line in @figure-discont, vibration in-plane)
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and an A#sub[1] mode (green line in @figure-discont, vibration along z-direction).
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When the light is incident along the y direction,
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the relevant phonon modes are those along the #{sym.Gamma}-K line and only symmetry of C#sub[2v] applies.
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The mode vibration in z direction (A#sub[1] mode in C#sub[2v])
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will have much lower frequency (green line in @figure-discont),
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and the E#sub[1] mode C#sub[6v] will degenerate into two modes in C#sub[2v],
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including B#sub[2] mode (blue line in @figure-discont, vibration along x direction)
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and B#sub[1] mode (red line in @figure-discont, vibration in y direction).
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When the light is incident along random directions,
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no symmetry applies, and there will be three phonon modes.
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When the light is incident along other directions, symmetry in plane was broken and C#sub[6v] symmetry no longer holds,
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and there will be three phonon modes in theory.
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For example, when the light is incident along the y direction (phonon modes on the #{sym.Gamma}-K line),
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symmetry of C#sub[2v] applies and three modes exist in dispersion curves,
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including an A#sub[1] mode (green line in @figure-discont, vibration along z direction),
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a B#sub[2] mode (blue line in @figure-discont, vibration along x direction),
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and a B#sub[1] mode (red line in @figure-discont, vibration in y direction).
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When the light is incident along a direction between z and y,
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three phonon modes will exist, but vibration in the mixed direction.
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// 有许多沿 z 方向入射的 4H-SiC 拉曼实验,它们都观察到了两个峰。
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// 但没有人在实验上观察到沿其它方向入射的三个峰。
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// 在我们的实验中,我们发现第三个峰只有在聚焦到样品内部时才会出现。
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// 根据它在不同偏振下的可见性和距离 E2 主峰的距离,我们认定它就是我们要找的峰。
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// 极性声子对入射方向非常敏感。拉曼光谱中位置相近的峰实际上是不同的振动方向。我们预言,当入射光斜时,LO 峰会向高频移动,并且会出现三个峰。
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// 实验验证了我们的猜想。如图,LO 峰如何如何。
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// 此外,这个 TO 峰可以通过聚焦到内部来得到。
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// 我们还注意到,TO 峰会因为偏振方向的不同而发生一些偏移。这可以由双折射解释。
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// 极性声子模式还会与载流子发生较强的相互作用。
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@figure-discont
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#include "table-pol.typ"
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