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2025-05-27 15:01:18 +08:00
parent d6cb983427
commit 511c274be1
2 changed files with 30 additions and 20 deletions

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@@ -10,7 +10,7 @@ This approximation is widely adopted (cite) and justified by the fact that,
see orange dotted line in @figure-discont),
and their dispersion at #sym.Gamma point is continuous with vanishing derivatives.
Therefore, negligible-polar phonons involved in Raman processes
have nearly indistinguishable frequencies and vibration amplitudes from those at the #sym.Gamma point.
have nearly indistinguishable properties from those at the #sym.Gamma point.
#include "figure-discont.typ"
@@ -85,3 +85,5 @@ Besides, there are small peeks at xxx,
#include "table-nopol.typ"
#include "figure-raman.typ"
// TODO: 解释为什么 E1 可以看到

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@@ -8,28 +8,36 @@
// 若考虑到到入射光不是严格沿着 z 方向,而是有一个小的角度(例如 10 度),则此时有一个声子模式沿着 x 方向,另外两个声子模式则为 y-z 两个方向的混合。
// (没有在图上表示)
Strong-polar phonons heavily depend on the direction of their wavevectors
due to long-range Coulomb interactions between atoms in semiconductors.
This causes the strong-polar phonon modes corresponding to different incident light directions
having different frequencies (i.e., discontinuity of colored lines near #sym.Gamma point in @figure-discont),
and their vibration directions also vary accordingly.
For incident laser propagating along the z direction,
the relevant phonon modes are those along the A-#sym.Gamma line and symmetry of C#sub[6v] point group applies,
leading to two modes (two peeks in Raman spectra),
Strong-polar phonon modes caused by different incident light directions are different,
due to long-range Coulomb interactions between atoms in semiconductors,
showing discontinuity in the scattering spectra near the #sym.Gamma point (see @figure-discont).
For incident light propagating along the z direction (phonon modes on the A-#sym.Gamma line),
symmetry of C#sub[6v] point group applies and leading to two modes (two peeks in Raman spectra),
including an E#sub[1] mode (pink line in @figure-discont, vibration in-plane)
and an A#sub[1] mode (green line in @figure-discont, vibration along z-direction).
When the light is incident along the y direction,
the relevant phonon modes are those along the #{sym.Gamma}-K line and only symmetry of C#sub[2v] applies.
The mode vibration in z direction (A#sub[1] mode in C#sub[2v])
will have much lower frequency (green line in @figure-discont),
and the E#sub[1] mode C#sub[6v] will degenerate into two modes in C#sub[2v],
including B#sub[2] mode (blue line in @figure-discont, vibration along x direction)
and B#sub[1] mode (red line in @figure-discont, vibration in y direction).
When the light is incident along random directions,
no symmetry applies, and there will be three phonon modes.
When the light is incident along other directions, symmetry in plane was broken and C#sub[6v] symmetry no longer holds,
and there will be three phonon modes in theory.
For example, when the light is incident along the y direction (phonon modes on the #{sym.Gamma}-K line),
symmetry of C#sub[2v] applies and three modes exist in dispersion curves,
including an A#sub[1] mode (green line in @figure-discont, vibration along z direction),
a B#sub[2] mode (blue line in @figure-discont, vibration along x direction),
and a B#sub[1] mode (red line in @figure-discont, vibration in y direction).
When the light is incident along a direction between z and y,
three phonon modes will exist, but vibration in the mixed direction.
// 有许多沿 z 方向入射的 4H-SiC 拉曼实验,它们都观察到了两个峰。
// 但没有人在实验上观察到沿其它方向入射的三个峰。
// 在我们的实验中,我们发现第三个峰只有在聚焦到样品内部时才会出现。
// 根据它在不同偏振下的可见性和距离 E2 主峰的距离,我们认定它就是我们要找的峰。
// 极性声子对入射方向非常敏感。拉曼光谱中位置相近的峰实际上是不同的振动方向。我们预言当入射光斜时LO 峰会向高频移动,并且会出现三个峰。
// 实验验证了我们的猜想。如图LO 峰如何如何。
// 此外,这个 TO 峰可以通过聚焦到内部来得到。
// 我们还注意到TO 峰会因为偏振方向的不同而发生一些偏移。这可以由双折射解释。
// 极性声子模式还会与载流子发生较强的相互作用。
@figure-discont
#include "table-pol.typ"