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@@ -10,7 +10,7 @@ This approximation is widely adopted (cite) and justified by the fact that,
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see orange dotted line in @figure-discont),
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and their dispersion at #sym.Gamma point is continuous with vanishing derivatives.
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Therefore, negligible-polar phonons involved in Raman processes
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have nearly indistinguishable properties from those at the #sym.Gamma point.
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have nearly indistinguishable frequencies and vibration amplitudes from those at the #sym.Gamma point.
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#include "figure-discont.typ"
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@@ -8,6 +8,26 @@
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// 若考虑到到入射光不是严格沿着 z 方向,而是有一个小的角度(例如 10 度),则此时有一个声子模式沿着 x 方向,另外两个声子模式则为 y-z 两个方向的混合。
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// (没有在图上表示)
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Strong-polar phonons heavily depend on the direction of their wavevectors
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due to long-range Coulomb interactions between atoms in semiconductors.
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This causes the strong-polar phonon modes corresponding to different incident light directions
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having different frequencies (i.e., discontinuity of colored lines near #sym.Gamma point in @figure-discont),
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and their vibration directions also vary accordingly.
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For incident laser propagating along the z direction,
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the relevant phonon modes are those along the A-#sym.Gamma line and symmetry of C#sub[6v] point group applies,
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leading to two modes (two peeks in Raman spectra),
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including an E#sub[1] mode (pink line in @figure-discont, vibration in-plane)
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and an A#sub[1] mode (green line in @figure-discont, vibration along z-direction).
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When the light is incident along the y direction,
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the relevant phonon modes are those along the #{sym.Gamma}-K line and only symmetry of C#sub[2v] applies.
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The mode vibration in z direction (A#sub[1] mode in C#sub[2v])
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will have much lower frequency (green line in @figure-discont),
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and the E#sub[1] mode C#sub[6v] will degenerate into two modes in C#sub[2v],
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including B#sub[2] mode (blue line in @figure-discont, vibration along x direction)
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and B#sub[1] mode (red line in @figure-discont, vibration in y direction).
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When the light is incident along random directions,
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no symmetry applies, and there will be three phonon modes.
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// 极性声子模式还会与载流子发生较强的相互作用。
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@figure-discont
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