From b0dab166e9727814efd9be2e9f4b64f76b12164b Mon Sep 17 00:00:00 2001 From: chn Date: Mon, 29 Sep 2025 14:48:11 +0800 Subject: [PATCH] --- .gitignore | 1 - paper/method/axis/default.typ | 2 +- paper/method/experiment/default.typ | 23 ++++++++++++++++++ paper/result/perfect/figure-raman.typ | 8 ++++++ paper/result/perfect/non-polar/figure-e1.typ | 12 +++++++++ .../perfect/non-polar/figure-nopo-diff.typ | 12 +++++++++ .../result/perfect/non-polar/table-nopol.typ | 21 ++++------------ 画图/弱极性不同方向偏移/fwhm_E22.csv | 4 --- 画图/弱极性不同方向偏移/plot.ipynb | 4 +-- 画图/弱极性不同方向偏移/shift_A11.csv | 4 --- 画图/弱极性不同方向偏移/shift_E21.csv | 4 --- 画图/弱极性不同方向偏移/shift_E22.csv | 4 --- 画图/拉曼结果拟合/250910/1/readme.txt | 3 +++ 画图/拉曼结果拟合/250910/1/readme.txt.txt | 3 --- 画图/拉曼结果拟合/250910/3/readme.txt.txt | 3 --- 画图/拉曼结果拟合/250923/1/joined_x.txt | 11 +++++++++ 画图/拉曼结果拟合/250923/1/joined_y.txt | 11 +++++++++ 画图/拉曼结果拟合/250923/2/joined_x.txt | 11 +++++++++ 画图/拉曼结果拟合/250923/2/joined_y.txt | 11 +++++++++ .../250923/fitting_raman_tensor.ipynb | 3 +++ .../250923/fitting_raman_tensor.ods | Bin 0 -> 28274 bytes 画图/拉曼结果拟合/250923/join_and_move.ipynb | 3 +++ 画图/拉曼结果拟合/250923/plot.ipynb | 3 +++ 画图/拉曼结果拟合/250923/shift_A11.txt | 2 ++ 画图/拉曼结果拟合/250923/shift_E21.txt | 2 ++ 画图/拉曼结果拟合/250923/shift_E22.txt | 2 ++ 画图/拉曼结果拟合/README.md | 7 +++--- 27 files changed, 128 insertions(+), 46 deletions(-) create mode 100644 paper/result/perfect/figure-raman.typ create mode 100644 paper/result/perfect/non-polar/figure-e1.typ create mode 100644 paper/result/perfect/non-polar/figure-nopo-diff.typ delete mode 100644 画图/弱极性不同方向偏移/fwhm_E22.csv delete mode 100644 画图/弱极性不同方向偏移/shift_A11.csv delete mode 100644 画图/弱极性不同方向偏移/shift_E21.csv delete mode 100644 画图/弱极性不同方向偏移/shift_E22.csv create mode 100755 画图/拉曼结果拟合/250910/1/readme.txt delete mode 100755 画图/拉曼结果拟合/250910/1/readme.txt.txt delete mode 100755 画图/拉曼结果拟合/250910/3/readme.txt.txt create mode 100644 画图/拉曼结果拟合/250923/1/joined_x.txt create mode 100644 画图/拉曼结果拟合/250923/1/joined_y.txt create mode 100644 画图/拉曼结果拟合/250923/2/joined_x.txt create mode 100644 画图/拉曼结果拟合/250923/2/joined_y.txt create mode 100644 画图/拉曼结果拟合/250923/fitting_raman_tensor.ipynb create mode 100644 画图/拉曼结果拟合/250923/fitting_raman_tensor.ods create mode 100644 画图/拉曼结果拟合/250923/join_and_move.ipynb create mode 100644 画图/拉曼结果拟合/250923/plot.ipynb create mode 100644 画图/拉曼结果拟合/250923/shift_A11.txt create mode 100644 画图/拉曼结果拟合/250923/shift_E21.txt create mode 100644 画图/拉曼结果拟合/250923/shift_E22.txt diff --git a/.gitignore b/.gitignore index 0b805b2..8263cbf 100644 --- a/.gitignore +++ b/.gitignore @@ -1,3 +1,2 @@ .~lock* .vscode -result diff --git a/paper/method/axis/default.typ b/paper/method/axis/default.typ index 54702a9..5f9382a 100644 --- a/paper/method/axis/default.typ +++ b/paper/method/axis/default.typ @@ -9,7 +9,7 @@ 同时，我们定义 a 轴与 x 轴平行，b 轴与 a 轴夹角为 120 度。 在此定义下，晶圆的切边沿 x 方向（即 [$11 overline(2) 0$] 方向）， 台阶流外延过程中台阶台阶边沿平行于 y 方向（即 [$1 overline(1) 00$] 方向），生长方向为 x 方向（即 [$11 overline(2) 0$]）。 -此定义与 material projects 数据库以及大部分文献中的定义一致，而与其它一些文献中的定义不一致。 +此定义与 material projects 数据库以及大部分文献中的定义一致，而与其它一些文献和数学教科书中的定义不同，因此在使用时需要仔细确认。 （最后一行补充参考文献）。 The axes in our study need to be clearly defined due to the anisotropy of 4H-SiC. diff --git a/paper/method/experiment/default.typ b/paper/method/experiment/default.typ index b7ef53b..4be7d69 100644 --- a/paper/method/experiment/default.typ +++ b/paper/method/experiment/default.typ @@ -34,3 +34,26 @@ The integration time was set to 60 seconds for normal and edge incidence, 偏振的配置？ #include "figure-incidence.typ" + +使用以下公式来从实验结果估计拉曼张量： + +$ + abs(S_i) = C I_i (nu_i (1-exp(-(h nu_i)/(k T))))/((nu - nu_i)^4) +$ + +其中 $S_i$ 是对应于入射方向和偏振的拉曼张量的组分，$I_i$ 是散射光强度（对应于峰积分），$nu_i$ 是声子频率，$nu$ 是激光的频率，$T$ 是样品温度。 +$C$ 是一个包含入射光强度在内的常数，在本文中使用 4H-SiC 正入射 zxxz 的特征峰来校准 $C$ 的值。 + +在本文中，涉及到对 A1 E1 E2 模式的拉曼张量的估计。 +在本文中，对于 E2 和 A1 在面内的拉曼张量，我们使用正入射 zyyz来估计； +对于 E1 的拉曼张量，我们使用侧入射 xyzx 来估计； +对于A1在面外的拉曼张量，我们使用侧入射 xzzx 来估计。 +使用4H-SiC的特征峰来校准 K 值。 + +todo +将拟合结果填充到表格中 +关于正入射和侧入射的对比：拟合得到结果、画曲线图、画箱图 +极性模式对比。有两个方面需要对比。一个是，正、侧入射的不同，说明分裂的大小与我们的计算是否一致，LOPC是否会在其它偏振下出现；一个是，对正入射时E1的出现作解释。 + + +探索：为什么对于A1的拟合，结果会差两倍？ \ No newline at end of file diff --git a/paper/result/perfect/figure-raman.typ b/paper/result/perfect/figure-raman.typ new file mode 100644 index 0000000..82a8d8f --- /dev/null +++ b/paper/result/perfect/figure-raman.typ @@ -0,0 +1,8 @@ +#figure( + image("/画图/拉曼整体图/embed.svg"), + caption: [ + Phonon modes and corresponding Raman spectra of 4H-SiC. + (a)-(b) Raman spectra with (a) normal and (b) edge incidence configurations. + ], + placement: none +) diff --git a/paper/result/perfect/non-polar/figure-e1.typ b/paper/result/perfect/non-polar/figure-e1.typ new file mode 100644 index 0000000..1abfcab --- /dev/null +++ b/paper/result/perfect/non-polar/figure-e1.typ @@ -0,0 +1,12 @@ +#figure( + image("/画图/E1减小/embed.svg"), + caption: [ + (a) Phonon dispersion of 4H-SiC along the A–#sym.Gamma–K high-symmetry path. + Gray lines represent negligible-polar phonon modes, + while colored lines indicate strong-polar phonon modes. + (b) Magnified view of the boxed region in (a). + The orange dashed lines mark the phonon wavevectors involved in Raman scattering + with incident light along the z- and y-directions. + ], + placement: none +) diff --git a/paper/result/perfect/non-polar/figure-nopo-diff.typ b/paper/result/perfect/non-polar/figure-nopo-diff.typ new file mode 100644 index 0000000..ab1743e --- /dev/null +++ b/paper/result/perfect/non-polar/figure-nopo-diff.typ @@ -0,0 +1,12 @@ +#figure( + image("/画图/弱极性不同方向偏移/main.svg"), + caption: [ + (a) Phonon dispersion of 4H-SiC along the A–#sym.Gamma–K high-symmetry path. + Gray lines represent negligible-polar phonon modes, + while colored lines indicate strong-polar phonon modes. + (b) Magnified view of the boxed region in (a). + The orange dashed lines mark the phonon wavevectors involved in Raman scattering + with incident light along the z- and y-directions. + ], + placement: none +) diff --git a/paper/result/perfect/non-polar/table-nopol.typ b/paper/result/perfect/non-polar/table-nopol.typ index bfc3a70..2135b25 100644 --- a/paper/result/perfect/non-polar/table-nopol.typ +++ b/paper/result/perfect/non-polar/table-nopol.typ @@ -1,11 +1,4 @@ -// 这个表格里的数据来自： -// 对于 E2，使用正入射 zyyz zyxz 的结果的平均。 -// 对于 E1，使用肩入射 yzxy 的结果。 -// 对于 A1，使用肩入射 yzzy 正入射 zyyz 的结果的平均。 -// 结果来自 2509xx - - -// #page(flipped: false)[#rotate(-90deg, reflow: true)[#figure({ +// 拟合结果位于 画图/拉曼结果拟合/250923 #page(flipped: true)[#figure({ set text(size: 9pt); set par(justify: false); @@ -20,12 +13,11 @@ [Simulation (cm#super[-1])], // E2 E2 E1 A1 E1 E2 E2 A1 [190.51], [197.84], [257.35], m2[591.90], [746.91], [756.25], [764.33], m2[812.87], - [Experiment (cm#super[-1], averaged)], + [Experiment (cm#super[-1])], // E2 E2 E1 A1 E1 E2 E2 A1 [195.5], [203.3], [269.7], m2[609.5], [Invisible], [776], [Invisible], m2[839], // E2 E2 E1 A1 E1 E2 E2 A1 [Error (%)], [2.6], [2.7], [4.6], m2[2.9], [-], [2.5], [-], m2[3.1], - // TODO: 重新检查数据是否正确（主要是正负号） table.cell(rowspan: 4)[*Raman Tensor*], [Non-zero components], // E2 E2 E1 A1 @@ -38,15 +30,12 @@ // E1 E2 E2 A1 [$-2epsilon_1+2zeta_1$], [$bold(8a_2)+2epsilon_2-2zeta_2-4eta_2$], [$-2epsilon_2+2zeta_2$], [$-2zeta_5$], [$-2zeta_6$], [Calculation result (a.u.)], - // TODO: 改正正负号 // E2 E2 E1 A1 E1 E2 E2 A1 [0.17], [1.13], [2.43], [2.83], [1.79], [0.09], [88.54], [0.50], [0.01], [1.78], - [Experiment result #linebreak() (a.u., averaged)], - // TODO: 填充 - // E2 E2 E1 A1 E1 E2 E2 A1 - [], [], [], [], [], [Invisible], [], [Invisible], [Invisible], [], + [Experiment result #linebreak() (a.u.)], + // E2 E2 E1 A1 E1 E2 E2 A1 + [0.15], [1.11], [], [1.64], [], [Invisible], [88.54], [Invisible], [Invisible], [], )}, caption: [Negaligible-polarized Phonons at $Gamma$ Point.], )] -// TODO: 从多个方向的实验中取得平均值。 diff --git a/画图/弱极性不同方向偏移/fwhm_E22.csv b/画图/弱极性不同方向偏移/fwhm_E22.csv deleted file mode 100644 index 3c60e8e..0000000 --- a/画图/弱极性不同方向偏移/fwhm_E22.csv +++ /dev/null @@ -1,4 +0,0 @@ -1.7608270175274945 1.7095382677800082 1.6908206133855936 1.641072964651852 1.6077984597054702 -1.8521285781470913 1.8070926863375696 1.8063564129426537 1.7796436816826098 1.7863596199454495 -1.8550653942136455 1.8454179607235797 1.8355798460139852 1.8640304200694087 2.1953176226936186 -1.8046549945528232 1.702570082702504 1.790691823550824 1.805662743000825 2.1233278447896313 diff --git a/画图/弱极性不同方向偏移/plot.ipynb b/画图/弱极性不同方向偏移/plot.ipynb index 5430e5b..7331e99 100644 --- a/画图/弱极性不同方向偏移/plot.ipynb +++ b/画图/弱极性不同方向偏移/plot.ipynb @@ -1,3 +1,3 @@ version https://git-lfs.github.com/spec/v1 -oid sha256:766076dd433300bd47ec770ddc026a630dae235458326ac866e95a80d835a005 -size 2484946 +oid sha256:cb661f5bf4080c6050a5dc6728696f9b2bcb1eedee6726be32715e7ee32376b9 +size 835000 diff --git a/画图/弱极性不同方向偏移/shift_A11.csv b/画图/弱极性不同方向偏移/shift_A11.csv deleted file mode 100644 index b1bd9ac..0000000 --- a/画图/弱极性不同方向偏移/shift_A11.csv +++ /dev/null @@ -1,4 +0,0 @@ -610.1213008890824 610.1330681678368 610.1588530411506 610.1811021981093 610.1986449965905 -609.7440349023198 609.9115498133125 609.956740868125 609.9158791976113 610.0334707759941 -609.6677307789029 609.6669096041305 609.7130323351229 609.7274691263951 609.4912325733311 -609.7087116252412 609.5493648779523 609.632471522247 609.7291873589254 609.4961232284547 diff --git a/画图/弱极性不同方向偏移/shift_E21.csv b/画图/弱极性不同方向偏移/shift_E21.csv deleted file mode 100644 index 01da129..0000000 --- a/画图/弱极性不同方向偏移/shift_E21.csv +++ /dev/null @@ -1,4 +0,0 @@ -195.73602107894294 195.74080631709137 195.77557988756905 195.76148803134245 195.76983155098773 -195.96055989744724 195.85259578794742 195.7927026486199 195.83645434579918 195.76794597230077 -196.19825656128967 196.20368948678166 196.19343990422314 196.16722948184966 196.0690751103817 -195.97757968839247 196.74028227696692 196.3986248349401 196.26794625826986 195.98019647684944 diff --git a/画图/弱极性不同方向偏移/shift_E22.csv b/画图/弱极性不同方向偏移/shift_E22.csv deleted file mode 100644 index 8e13403..0000000 --- a/画图/弱极性不同方向偏移/shift_E22.csv +++ /dev/null @@ -1,4 +0,0 @@ -203.6801432038987 203.68814481324 203.68505961884634 203.69299952913238 203.6904003764694 -203.91071868059444 203.765195365188 203.73916579371567 203.8009438952096 203.70415932586553 -203.73665069017437 203.74307378471798 203.7412374475013 203.7355035381401 203.68224371967472 -203.68505533371479 203.83431521382425 203.71910427658776 203.79953992752039 203.66963877731052 diff --git a/画图/拉曼结果拟合/250910/1/readme.txt b/画图/拉曼结果拟合/250910/1/readme.txt new file mode 100755 index 0000000..103d30e --- /dev/null +++ b/画图/拉曼结果拟合/250910/1/readme.txt @@ -0,0 +1,3 @@ +Si片，间隔5um取5个点 +针孔 100 正焦 zyyz +前两个结果为170-1100（需要移动光谱），第三个结果为400-600（不需要移动光谱）。 \ No newline at end of file diff --git a/画图/拉曼结果拟合/250910/1/readme.txt.txt b/画图/拉曼结果拟合/250910/1/readme.txt.txt deleted file mode 100755 index 70b7231..0000000 --- a/画图/拉曼结果拟合/250910/1/readme.txt.txt +++ /dev/null @@ -1,3 +0,0 @@ -SiƬ5umȡ5 - 100 zyyz -ǰΪ170-1100ҪƶףΪ400-600Ҫƶף \ No newline at end of file diff --git a/画图/拉曼结果拟合/250910/3/readme.txt.txt b/画图/拉曼结果拟合/250910/3/readme.txt.txt deleted file mode 100755 index 305b6a4..0000000 --- a/画图/拉曼结果拟合/250910/3/readme.txt.txt +++ /dev/null @@ -1,3 +0,0 @@ -ԸƬĽ -1dzĵףʣµľǰ˳ -һֲ11֡ \ No newline at end of file diff --git a/画图/拉曼结果拟合/250923/1/joined_x.txt b/画图/拉曼结果拟合/250923/1/joined_x.txt new file mode 100644 index 0000000..13029dc --- /dev/null +++ b/画图/拉曼结果拟合/250923/1/joined_x.txt @@ -0,0 +1,11 @@ +151.300143 151.820143 152.339143 152.859143 153.379143 153.899143 154.418143 154.938143 155.458143 155.977143 156.497143 157.014143 157.534143 158.053143 158.573143 159.092143 159.611143 160.131143 160.650143 161.169143 161.687143 162.206143 162.725143 163.244143 163.763143 164.283143 164.802143 165.319143 165.838143 166.357143 166.876143 167.395143 167.914143 168.430143 168.949143 169.468143 169.987143 170.506143 171.022143 171.541143 172.060143 172.578143 173.095143 173.613143 174.132143 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