From 87f25a4121c99bca4321c6003a26e96bdeb881f5 Mon Sep 17 00:00:00 2001 From: chn Date: Fri, 27 Jun 2025 11:10:12 +0800 Subject: [PATCH] --- TODO.md | 10 ++++++++++ paper/method/default.typ | 21 ++++++++++----------- 2 files changed, 20 insertions(+), 11 deletions(-) create mode 100644 TODO.md diff --git a/TODO.md b/TODO.md new file mode 100644 index 0000000..356ff1b --- /dev/null +++ b/TODO.md @@ -0,0 +1,10 @@ +* [ ] 文本 + * [ ] method + * [ ] 无缺陷和缺陷的模型大小、缺陷结构 + * [ ] 第一性原理计算和声子计算的工具 +* [ ] 实验 + * [ ] 实验 + * [ ] 测试不同片子的背面 LOPC,确认它们的掺杂是否相同 + * [ ] 拟合 + * [ ] 拟合最后一次正入射的结果,确定峰位移与掺杂等的关系 + * [ ] 拟合带 LOPC 的 LO diff --git a/paper/method/default.typ b/paper/method/default.typ index d66f506..fff01cc 100644 --- a/paper/method/default.typ +++ b/paper/method/default.typ @@ -22,30 +22,29 @@ The Si/C ratios of the five wafers during growth were 0.7, 1.2, 1.6, 2.4, and 2. 拉曼设备的型号是 LabRAM HR Evolution,使用背散射。 大部分实验中,我们使用 532 nm 的激光,少部分实验中使用 325 nm 的激光以观测紫外拉曼。 有三个不同的入射配置,包括正入射、掠入射、边入射。 -考虑到 4 度斜切和 4H-SiC 几乎各向同性的折射率() @shaffer_refractive_1971 , +考虑到 4 度斜切和 4H-SiC 几乎各向同性的折射率(2.73) @shaffer_refractive_1971 ,掠入射的入射角大约为 25 度。 在正散射过程中,我们使用 100 微米的共焦针孔,以尽可能提高 z 方向的分辨率 @song_depth_2020。 All our Raman experiments were performed using a LabRAM HR Evolution system with back-scattering configuration, where collected scattered light has a reversed wavevector direction compared to the incident light. A 532 nm laser was used in most experiments, while a 325 nm laser was used to observe Raman signals under ultraviolet excitation. -Three different incidece configurations were used, as shown in @figure-incidence: - normal incidence, where the laser beam is perpendicular to the epitaxial surface; +Three different incidece configurations were used, as shown in @figure-incidence, + including normal incidence, where the laser beam is perpendicular to the epitaxial surface; grazing incidence, where the laser beam is nearly parallel to the epitaxial surface; and edge incidence, where the laser beam is incident at the edge of the wafer, instead of the epitaxial surface. -Taking the -During the experiments, a 100 μm confocal pinhole was used to improve the z-direction resolution @song_depth_2020. - - and the refracted light propagates with about 25 #sym.degree to the c axis; +Taking the 4° offcut angle + and the nearly isotropic refractive index 2.73 of 4H-SiC @shaffer_refractive_1971 into account, + the wavevector in 4H-SiC during grazing incidence is about 25° to the c axis. +During normal incidence, a 100 μm confocal pinhole was used to improve the z-direction resolution @song_depth_2020; + while during other configurations, 200 μm confocal pinhole was used to improve the signal-to-noise ratio. #include "figure-incidence.typ" == Simulation details -无缺陷的模型大小。带缺陷的情况下,模型大小,每个模型的代号和缺陷结构。 +无缺陷的声子在多大的模型中计算。 +带缺陷的情况下,模型大小,每个模型的代号和缺陷结构。 第一性原理计算使用 VASP,使用 PBE PAW,平面波截断能,K 点网格,涂抹,自洽和弛豫的 threshold。 声子计算使用 phonopy phono3py ufo,BEC 修正的算法。 - -// 在略入射的过程中,角度的关系不大(即使是 60 度入射,和 90 度入射差别也不大)。因此我们按照折射角 20 度的结果计算。 -// 考虑到斜切,则大约是 24 度。